"Bruce Sterling - Buckymania" - читать интересную книгу автора (Sterling Bruce)1985, in Houston, Texas, in honor of the American engineer, inventor,
and delphically visionary philosopher, R. Buckminster Fuller. "Buckminsterfullerene," or C60, is the best-known fullerene. It's very round, the roundest molecule known to science. Sporting what is technically known as "truncated icosahedral structure," C60 is the most symmetric molecule possible in three-dimensional Euclidean space. Each and every molecule of "Buckminsterfullerene" is a hollow, geodesic sphere of sixty carbon atoms, all identically linked in a spherical framework of twelve pentagons and twenty hexagons. This molecule looks exactly like a common soccerball, and was therefore nicknamed a "buckyball" by delighted chemists. A free buckyball rotates merrily through space at one hundred million revolutions per second. It's just over one nanometer across. Buckminsterfullerene by the gross forms a solid crystal, is stable at room temperature, and is an attractive mustard-yellow color. A heap of crystallized buckyballs stack very much like pool balls, and are as soft as graphite. It's thought that buckyballs will make good lubricants -- something like molecular ball bearings. When compressed, crystallized buckyballs squash and flatten readily, down to about seventy percent of their volume. They then refused to move any further and become extremely hard. Just *how* hard is not yet established, but according to chemical theory, They may make good shock absorbers, or good armor. But this is only the beginning of carbon's multifarious oddities in the playful buckyball field. Because buckyballs are hollow, their carbon framework can be wrapped around other, entirely different atoms, forming neat molecular cages. This has already been successfully done with certain metals, creating the intriguing new class of "metallofullerites." Then there are buckyballs with a carbon or two knocked out of the framework, and replaced with metal atoms. This "doping" process yields a galaxy of so-called "dopeyballs." Some of these dopeyballs show great promise as superconductors. Other altered buckyballs seem to be organic ferromagnets. A thin film of buckyballs can double the frequency of laser light passing through it. Twisted or deformed buckyballs might act as optical switches for future fiber-optic networks. Buckyballs with dangling branches of nickel, palladium, or platinum may serve as new industrial catalysts. The electrical properties of buckyballs and their associated compounds are very unusual, and therefore very promising. Pure C60 is an insulator. Add three potassium atoms, and it becomes a low- temperature superconductor. Add three more potassium atoms, and it becomes an insulator again! There's already excited talk in industry of |
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